Method of regeneration of DMSO- d 6

D. A. Lomov; Ломов Д. А.

doi:10.31857/S0514749225030171

Method of regeneration of DMSO-d₆

Authors: Lomov D.A.¹
Affiliations:
1. Litvinenko Institute of Physical-Organic and Coal Chemistry
Issue: Vol 61, No 3 (2025)
Pages: 341-344
Section: КРАТКОЕ СООБЩЕНИЕ
URL: https://bioethicsjournal.ru/0514-7492/article/view/687767
DOI: https://doi.org/10.31857/S0514749225030171
EDN: https://elibrary.ru/EVDNIC
ID: 687767

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Abstract
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Abstract

A method for regenerating DMSO-d₆ is proposed, based on the azeotropic distillation of water and volatile impurities with carbon tetrachloride and subsequent removal of impurities distilled from DMSO-d₆ by complexation with copper ions.

Keywords

DMSO-d₆, complexation, vacuum distillation, copper sulfate

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About the authors

D. A. Lomov

Litvinenko Institute of Physical-Organic and Coal Chemistry

Author for correspondence.
Email: lomov_dmitrii@mail.ru
ORCID iD: 0000-0001-9955-6225
Russian Federation, ul. Rosy Luxemburg, 70, Donetsk, 283048

References

Воловенко Ю.М., Карцев В.Г., Комаров И.В., Туров А.В., Хиля В.П. Спектроскопия ядерного магнитного резонанса для химиков М.: ICSPF, 2011, 64–75.
Сенюта С.А., Зонов Ю.А., Касаткин В.П., Кукушкин А.М., Пат. 1721049A1 (1990). СССР Б.И. 1992, 11; https://patenton.ru/patent/ SU1721049A1
Bera D., Sarkar R., Dhar T., Saha P., Ghosh P., Mukhopadhyay C. Org. Biomol. Chem. 2024, 22, 3684–3692. doi: 10.1039/d4ob00383g
Gottlieb H.E., Kotlyar V., Nudelman A., J. Org. Chem. 1997, 62 (21), 7512–7215. doi: 10.1021/jo971176v
Fulmer G.R., Miller A.J.M., Sherden N.H., Gottlieb H.E., Nudelman A., Stoltz B.M., Bercaw J.E., Goldberg K.I. Organometallics. 2010, 29 (9), 2176–2179. doi: 10.1021/om100106e
Malik M., Switlicka A., Bienko A., Komarnicka U.K., Bienko D., Koziel S., Kyziol A., Mazur T., Machura B. RSC Adv. 2022, 12, 27648–27665. doi: 10.1039/d2ra05133h
Novoa-Ramírez C.S., Silva-Becerril A., González-Ballesteros M.M., Gomez-Vidal V., Flores-Álamo M., Ortiz-Frade L., Gracia-Mora J., Ruiz-Azuara L., J. Inorg. Biochem. 2023, 242, 112097. doi: 10.1016/j.jinorgbio.2022.112097
Кукушкин В.Ю., Кукушкин Ю.Н. Теория и практика синтеза координационных соединений. Л.: Наука, 1990, 77.
Chaudhry M., Persson I., J. Chem. Soc. Faraday Trans. 1994, 90, 2243–2248. doi: 10.1039/FT9949002243
Bravo J.A., Vila J.L., Flores Y., Bolivian J. of Chem. 2017, 34 (4), 123–131.