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Kinetic Study of para-tert-Butylcumene Oxidation in the Presence of N-Hydroxyphthalimide
- Authors: Frolov А.S.1, Kurganova E.A.1, Sapunov V.N.2, Kozlovskiy R.A.2, Koshel G.N.1, Yarkina E.M.1
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Affiliations:
- Yaroslavl State Technical University
- Mendeleev University of Chemical Technology of Russia
- Issue: Vol 64, No 6 (2023)
- Pages: 720-729
- Section: ARTICLES
- URL: https://bioethicsjournal.ru/0453-8811/article/view/660301
- DOI: https://doi.org/10.31857/S0453881123060072
- EDN: https://elibrary.ru/KTUAWJ
- ID: 660301
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Abstract
The kinetics of the oxidation of para-tert-butylcumene to hydroperoxide by molecular oxygen in the presence of N-hydroxyphthalimide has been studied. Based on the study of the regularities in the formation of hydroperoxide and non-target reaction products, a mathematical model of the process was obtained that adequately describes the change in the main components of the reaction concentration over time. The main role of N-hydroxyphthalimide is that it converts peroxide radicals into the corresponding hydroperoxides, thereby reducing the formation of non-target reaction products by reducing the quadratic termination rate. Simultaneously formed N-oxyphthalimide radicals increase the rate of hydrocarbon oxidation. Thus, the use of N-hydroxyphthalimide in hydrocarbon oxidation processes results in an increase in the rate and selectivity of hydroperoxide formation.
About the authors
А. S. Frolov
Yaroslavl State Technical University
Email: koshelgn@ystu.ru
Russia, 150023, Yaroslavl, Moskovskiy prosp., 88
E. A. Kurganova
Yaroslavl State Technical University
Email: koshelgn@ystu.ru
Russia, 150023, Yaroslavl, Moskovskiy prosp., 88
V. N. Sapunov
Mendeleev University of Chemical Technology of Russia
Email: koshelgn@ystu.ru
Russia, 125047, Moscow, Miusskaya square, 9, build. 6
R. A. Kozlovskiy
Mendeleev University of Chemical Technology of Russia
Email: koshelgn@ystu.ru
Russia, 125047, Moscow, Miusskaya square, 9, build. 6
G. N. Koshel
Yaroslavl State Technical University
Author for correspondence.
Email: koshelgn@ystu.ru
Russia, 150023, Yaroslavl, Moskovskiy prosp., 88
E. M. Yarkina
Yaroslavl State Technical University
Email: koshelgn@ystu.ru
Russia, 150023, Yaroslavl, Moskovskiy prosp., 88
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