<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE root>
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" article-type="research-article" dtd-version="1.2" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">Protection of Metals and Physical Chemistry of Surfaces</journal-id><journal-title-group><journal-title xml:lang="en">Protection of Metals and Physical Chemistry of Surfaces</journal-title><trans-title-group xml:lang="ru"><trans-title>Физикохимия поверхности и защита материалов</trans-title></trans-title-group></journal-title-group><issn publication-format="print">0044-1856</issn><issn publication-format="electronic">3034-6479</issn><publisher><publisher-name xml:lang="en">The Russian Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="publisher-id">695749</article-id><article-id pub-id-type="doi">10.31857/S0044185625040107</article-id><article-categories><subj-group subj-group-type="toc-heading"><subject>НАНОРАЗМЕРНЫЕ И НАНОСТРУКТУРИРОВАННЫЕ МАТЕРИАЛЫ И ПОКРЫТИЯ</subject></subj-group><subj-group subj-group-type="article-type"><subject>Research Article</subject></subj-group></article-categories><title-group><article-title xml:lang="en">Структура и свойства покрытий Zr–Ti–B–C–N, полученных методом импульсного магнетронного напыления</article-title><trans-title-group xml:lang="ru"><trans-title>Структура и свойства покрытий Zr–Ti–B–C–N, полученных методом импульсного магнетронного напыления</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Kiryukhantsev-Korneev</surname><given-names>P. V.</given-names></name><name xml:lang="ru"><surname>Кирюханцев-Корнеев</surname><given-names>Ф. В.</given-names></name></name-alternatives><email>kiruhancev-korneev@yandex.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Chertova</surname><given-names>A. D.</given-names></name><name xml:lang="ru"><surname>Чертова</surname><given-names>А. Д.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Kasymova</surname><given-names>V. M.</given-names></name><name xml:lang="ru"><surname>Касимова</surname><given-names>В. М.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Zabelina</surname><given-names>E. V.</given-names></name><name xml:lang="ru"><surname>Забелина</surname><given-names>Е. В.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Levinshov</surname><given-names>E. A.</given-names></name><name xml:lang="ru"><surname>Левашов</surname><given-names>Е. А.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff1"/></contrib></contrib-group><aff-alternatives id="aff1"><aff><institution xml:lang="en">National University of Science and Technology MISIS</institution></aff><aff><institution xml:lang="ru">Университет науки и технологий МИСИС</institution></aff></aff-alternatives><pub-date date-type="pub" iso-8601-date="2025-08-15" publication-format="electronic"><day>15</day><month>08</month><year>2025</year></pub-date><volume>61</volume><issue>4</issue><issue-title xml:lang="en">VOL 61, NO4 (2025)</issue-title><issue-title xml:lang="ru">ТОМ 61, №4 (2025)</issue-title><fpage>423</fpage><lpage>431</lpage><history><date date-type="received" iso-8601-date="2025-11-02"><day>02</day><month>11</month><year>2025</year></date></history><permissions><copyright-statement xml:lang="en">Copyright ©; 2025, Russian Academy of Sciences</copyright-statement><copyright-statement xml:lang="ru">Copyright ©; 2025, Российская академия наук</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="en">Russian Academy of Sciences</copyright-holder><copyright-holder xml:lang="ru">Российская академия наук</copyright-holder><ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/" start_date="2026-08-15"/></permissions><self-uri xlink:href="https://bioethicsjournal.ru/0044-1856/article/view/695749">https://bioethicsjournal.ru/0044-1856/article/view/695749</self-uri><abstract xml:lang="en"><p>Покрытия Zr–Ti–B–C–N были получены методом реакционного импульсного магнетронного напыления при частотах 0, 50 и 350 кГц. Покрытия содержали высокую суммарную концентрацию неметаллических элементов в диапазоне 80–84 ат.% и обладали плотной малодефектной аморфной структурой. В покрытиях преобладали связи B–N, B–C и Zr–O. Твердость покрытий составила 8–9 ГПа, модуль упругости и упругое восстановление находилось в пределах 126–144 ГПа и 36–40% соответственно. Наименьший коэффициент трения ~0,15 имело покрытие, осажденное при частоте 350 Гц. Максимальный оптический коэффициент пропускания ~90% показало покрытие, полученное при 50 кГц, характеризующееся минимальной толщиной и повышенной концентрацией кислорода. Покрытия Zr–Ti–B–C–N оптимального состава превосходили по коэффициенту пропускания образцы сравнения Zr–B–N.</p></abstract><trans-abstract xml:lang="ru"><p>Покрытия Zr–Ti–B–C–N были получены методом реакционного импульсного магнетронного напыления при частотах 0, 50 и 350 кГц. Покрытия содержали высокую суммарную концентрацию неметаллических элементов в диапазоне 80–84 ат.% и обладали плотной малодефектной аморфной структурой. В покрытиях преобладали связи B–N, B–C и Zr–O. Твердость покрытий составила 8–9 ГПа, модуль упругости и упругое восстановление находилось в пределах 126–144 ГПа и 36–40% соответственно. Наименьший коэффициент трения ~0,15 имело покрытие, осажденное при частоте 350 Гц. Максимальный оптический коэффициент пропускания ~90% показало покрытие, полученное при 50 кГц, характеризующееся минимальной толщиной и повышенной концентрацией кислорода. Покрытия Zr–Ti–B–C–N оптимального состава превосходили по коэффициенту пропускания образцы сравнения Zr–B–N.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>импульсное магнетронное напыление</kwd><kwd>аморфные покрытия</kwd><kwd>Zr–Ti–B–C–N</kwd><kwd>механические и трибологические характеристики</kwd><kwd>оптические свойства</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Работа выполнена при финансовой поддержке Российского научного фонда (проект № 24-13-00085).</funding-statement></funding-group></article-meta></front><body></body><back><ref-list><ref id="B1"><label>1.</label><mixed-citation>Kiryukhantsev-Korneev Ph.V., Sytchenko A.D., Kozlova N.S. et al. // Surface and Coatings Technology. 2022. V. 448. № 128849. https://doi.org/10.1016/j.surfcoat.2022.128849</mixed-citation></ref><ref id="B2"><label>2.</label><mixed-citation>Kiryukhantsev-Korneev Ph.V., Sytchenko A.D., Kozlova N.S. et al. // Surface and Coatings Technology. 2023. V. 474. № 130042. https://doi.org/10.1016/j.surfcoat.2023.130042</mixed-citation></ref><ref id="B3"><label>3.</label><mixed-citation>Sytchenko A.D., Kozlova N.S., Zabelina E.V. et al. // Surfaces and Interfaces. 2023. V. 37. № 102654. https://doi.org/10.1016/j.surfin.2023.102654</mixed-citation></ref><ref id="B4"><label>4.</label><mixed-citation>Chertova A.D., Levanov A.V., Meshkov B.B. et al. // Powder Metallurgy аnd Functional Coatings. 2024. V. 18. № 5. P. 37–43. https://doi.org/10.17073/1997-308X-2024-5-37–43</mixed-citation></ref><ref id="B5"><label>5.</label><mixed-citation>Houska J., Kohout J., Mares P. et al. // Thin Solid Films. 2015. V. 586. P. 22–27. https://doi.org/10.1016/j.tsf.2015.04.023</mixed-citation></ref><ref id="B6"><label>6.</label><mixed-citation>Mareš P., Vlček J., Houška J. et al. // Thin Solid Films. 2019. V. 688. № 137334. https://doi.org/10.1016/j.tsf.2019.05.053</mixed-citation></ref><ref id="B7"><label>7.</label><mixed-citation>Houška J., Kohout J., Vlček J. // Thin Solid Films. 2013. V. 542. P. 225–231. https://doi.org/10.1016/j.tsf.2013.07.010</mixed-citation></ref><ref id="B8"><label>8.</label><mixed-citation>Luo Q.H., Lu Y.H. // Applied Surface Science. 2011. V. 258. № 3. P. 1021–1026. https://doi.org/10.1016/j.apsusc.2011.08.053</mixed-citation></ref><ref id="B9"><label>9.</label><mixed-citation>Holzschuh H. // International Journal of Refractory Metals and Hard Materials. 2002. V. 20. № 2. P. 143–149. https://doi.org/10.1016/S0263-4368(02)00013-6</mixed-citation></ref><ref id="B10"><label>10.</label><mixed-citation>Zhang M., Jiang J., Houška J. et al. // Acta Materialia. 2014. V. 77. P. 212–222. https://doi.org/10.1016/j.actamat.2014.05.064</mixed-citation></ref><ref id="B11"><label>11.</label><mixed-citation>Lin J., Mishra B., Moore J.J. et al. // Surface and Coatings Technology. 2008. V. 203. № 5–7. P. 588–593. https://doi.org/10.1016/j.surfcoat.2008.06.083</mixed-citation></ref><ref id="B12"><label>12.</label><mixed-citation>Übleis A., Mitterer C., Ebner R. // Surface and Coatings Technology. 1993. V. 60. № 1–3. P. 571–576. https://doi.org/10.1016/0257-8972(93)90155-H</mixed-citation></ref><ref id="B13"><label>13.</label><mixed-citation>Movassagh-Alanagh F., Abdollah-Zadeh A., Zolbin M.A. et al. // Tribology International. 2023. V. 179. P. 108137. https://doi.org/10.1016/j.triboint.2022.108137</mixed-citation></ref><ref id="B14"><label>14.</label><mixed-citation>Holzschuh H. // Thin Solid Films. 2004. V. 469–470. P. 92–98. https://doi.org/10.1016/j.tsf.2004.08.077</mixed-citation></ref><ref id="B15"><label>15.</label><mixed-citation>Qiu L., Chen H., Zeng F. et al. // Surface and Coatings Technology. 2024. V. 480. № 130599. https://doi.org/10.1016/j.surfcoat.2024.130599</mixed-citation></ref><ref id="B16"><label>16.</label><mixed-citation>Rebholz C., Leyland A., Larour P. et al. // Surface and Coatings Technology. 1999. V. 116–119. P. 648–653. https://doi.org/10.1016/S0257-8972(99)00260-1</mixed-citation></ref><ref id="B17"><label>17.</label><mixed-citation>Wolfe D.E., Singh J., Narasimhan K. // Surface and Coatings Technology. 2003. V. 165. № 1. P. 8–25. https://doi.org/10.1016/S0257-8972(02)00666-7</mixed-citation></ref><ref id="B18"><label>18.</label><mixed-citation>Gu Jian-D., Chen Pei-L. // Surface and Coatings Technology. 2006. V. 200. № 10. P. 3341–3346. https://doi.org/10.1016/j.surfcoat.2005.07.049</mixed-citation></ref><ref id="B19"><label>19.</label><mixed-citation>Braic M., Braic V., Balaceanu M. et al. // Materials Chemistry and Physics. 2011. V. 126. № 3. P. 818–825. https://doi.org/10.1016/j.matchemphys.2010.12.036</mixed-citation></ref><ref id="B20"><label>20.</label><mixed-citation>Neidhardt J., Czigány Z., Sartory B. et al. // International Journal of Refractory Metals and Hard Materials. 2010. V. 28. № 1. P. 23–31. https://doi.org/10.1016/j.ijrmhm.2009.07.016</mixed-citation></ref><ref id="B21"><label>21.</label><mixed-citation>Kelly P.J. // Vacuum. 2000. V. 56. № 3. P. 159–172. https://doi.org/10.1016/S0042-207X(99)00189-X</mixed-citation></ref><ref id="B22"><label>22.</label><mixed-citation>Tan X.-Q., Liu J.-Y., Niu J.-R. et al. // Materials. 2018. V. 11. № 1953. https://doi.org/10.3390/ma11101953</mixed-citation></ref><ref id="B23"><label>23.</label><mixed-citation>Kiryukhantsev-Korneev Ph.V., Sheveyko A.N., Shvindina N.V. et al. // Ceramics International. 2018. V. 44. № 7. P. 7637–7646. https://doi.org/10.1016/j.ceramint.2018.01.187</mixed-citation></ref><ref id="B24"><label>24.</label><mixed-citation>Shtansky D.V., Kiryukhantsev-Korneev Ph.V., Sheveyko A.N. et al. // Surface and Coatings Technology. 2007. V. 202. № 4–7. P. 861–865. https://doi.org/10.1016/j.surfcoat.2007.05.064</mixed-citation></ref><ref id="B25"><label>25.</label><mixed-citation>Kiryukhantsev-Korneev Ph.V., Chertova A.D., Chudarin F.I. et al. // Surface and Coatings Technology. 2024. V. 484. № 130797. https://doi.org/10.1016/j.surfcoat.2024.130797</mixed-citation></ref><ref id="B26"><label>26.</label><mixed-citation>Iordanova I., Kelly P.J., Burova M. et al. // Thin Solid Films. 2012. V. 520. P. 5333–5339. https://doi.org/10.1016/j.tsf.2012.03.097</mixed-citation></ref><ref id="B27"><label>27.</label><mixed-citation>Audronis M., Kelly P.J., Leyland A. et al. // Thin Solid Films. 2006. V. 515. P. 1511–1516. https://doi.org/10.1016/j.tsf.2006.04.026</mixed-citation></ref><ref id="B28"><label>28.</label><mixed-citation>Richter N.A., Yang B., Barnard J.P. et al. // Applied Surface Science. 2023. V. 635. 157709. https://doi.org/10.1016/j.apsusc.2023.157709</mixed-citation></ref><ref id="B29"><label>29.</label><mixed-citation>Potanin A.Yu., Zaitsev A.A., Pogozhev Yu.S. et al. // Ceramics International. 2024. V. 50(22,B). P. 47433–47444. https://doi.org/10.1016/j.ceramint.2024.09.094</mixed-citation></ref><ref id="B30"><label>30.</label><mixed-citation>Kiryukhantsev-Korneev Ph.V., Sytchenko A.D., Sviridova T.A. et al. // Surface and Coatings Technology. 2022. V. 442. P. 128141. https://doi.org/10.1016/j.surfcoat.2022.128141</mixed-citation></ref><ref id="B31"><label>31.</label><mixed-citation>Kiryukhantsev-Korneev F.V. // Russian Journal of Non-Ferrous Metals. 2014. V. 55. P. 494–504. https://doi.org/10.3103/S1067821214050137</mixed-citation></ref><ref id="B32"><label>32.</label><mixed-citation>Chertova A.D., Sidorenko D.A., Levashov E.A. et al. // Vacuum. 2024. V. 227. № 113456. https://doi.org/10.1016/j.vacuum.2024.113456</mixed-citation></ref><ref id="B33"><label>33.</label><mixed-citation>García J., Moreno M., Wan W. et al. // Crystals. 2021. V. 11. № 158. https://doi.org/10.3390/cryst11020158</mixed-citation></ref><ref id="B34"><label>34.</label><mixed-citation>Ul-Hamid A. // J. Adv. Res. 2021. V. 29. P. 107–119. https://doi.org/10.1016/j.jare.2020.11.010</mixed-citation></ref><ref id="B35"><label>35.</label><mixed-citation>Tanno Y., Azushima A. // Surface and Coatings Technology. 2009. V. 203. № 23. P. 3631–3637. https://doi.org/10.1016/j.surfcoat.2009.05.043</mixed-citation></ref><ref id="B36"><label>36.</label><mixed-citation>Kim Y.-S., Park H.-J., Kim Y.-S. et al. // Coatings. 2024. V. 14. № 144. https://doi.org/10.3390/coatings14010144</mixed-citation></ref><ref id="B37"><label>37.</label><mixed-citation>Rogov A.V., Martynenko Y.V., Kapustin Y.V. et al. // Technical Physics. 2018. V. 63. P. 700–710. https://doi.org/10.1134/S1063784218050195</mixed-citation></ref><ref id="B38"><label>38.</label><mixed-citation>Lu Y.H., Liu Z.-J., Shen Y.G. // Acta Materialia. 2006. V. 54. P. 2897–2905. https://doi.org/10.1016/j.actamat.2006.02.027</mixed-citation></ref><ref id="B39"><label>39.</label><mixed-citation>Heau C., Terrat J.P. // Surface and Coatings Technology. 1998. V. 108–109. P. 332–339. https://doi.org/10.1016/S0257-8972(98)00621-5</mixed-citation></ref><ref id="B40"><label>40.</label><mixed-citation>Nandee R., Chowdhury M.A., Hossain N. et al. // Results in Engineering. 2024. V. 21. № 101738. https://doi.org/10.1016/J.RINENG.2023.101738</mixed-citation></ref><ref id="B41"><label>41.</label><mixed-citation>Pellegrinoa S., Trocellier P., Thomé L. et al. // Nuclear Instruments and Methods in Physics Research Section B. 2019. V. 454. P. 61–67. https://doi.org/10.1016/j.nimb.2019.02.012</mixed-citation></ref><ref id="B42"><label>42.</label><mixed-citation>Wdowik U.D., Twardowska A., Rajchel B. // Advances in Condensed Matter Physics. 2017. V. 1. № 4207301. https://doi.org/10.1155/2017/4207301</mixed-citation></ref><ref id="B43"><label>43.</label><mixed-citation>Rizzo A., Valerini D., Capodieci L. et al. // Applied Surface Science. 2018. V. 427. P. 994–1002 https://doi.org/10.1016/j.apsusc.2017.08.032</mixed-citation></ref><ref id="B44"><label>44.</label><mixed-citation>Dreiling I., Haug A., Holzschuh H. et al. // Surface and Coatings Technology. 2009. V. 204. № 6–7. P. 1008–1012. https://doi.org/10.1016/j.surfcoat.2009.05.029</mixed-citation></ref><ref id="B45"><label>45.</label><mixed-citation>Lin J., Mishra B., Moore J.J. et al. // Surface and Coatings Technology. 2008. V. 203. № 5–7. P. 588–593. https://doi.org/10.1016/j.surfcoat.2008.06.083</mixed-citation></ref><ref id="B46"><label>46.</label><mixed-citation>Vlček J., Steidl P., Kohout J. et al. // Surface and Coatings Technology. 2013. V. 215. P. 186–191. https://doi.org/10.1016/j.surfcoat.2012.08.084</mixed-citation></ref><ref id="B47"><label>47.</label><mixed-citation>Singh K., Krishnamurthy N., Suri A.K. // Tribology International. 2012. V. 50. P. 16–25. https://doi.org/10.1016/j.triboint.2011.12.023</mixed-citation></ref><ref id="B48"><label>48.</label><mixed-citation>Abad M., Sánchez-López J., Brizuela M. et al. // Thin Solid Films. 2010. V. 518. № 19. P. 5546–5552. https://doi.org/10.1016/j.tsf.2010.04.038</mixed-citation></ref><ref id="B49"><label>49.</label><mixed-citation>Huang S., Zhao Q., Lin C. et al. // Materials Science and Engineering A. 2021. V. 818. № 141394. https://doi.org/10.1016/j.msea.2021.141394</mixed-citation></ref><ref id="B50"><label>50.</label><mixed-citation>Vanegas P.H.S., Calderon V.S., Alfonso O.J.E. et al. // Applied Surface Science. 2019. V. 481. P. 1249–1259. https://doi.org/10.1016/J.APSUSC.2019.03.128</mixed-citation></ref></ref-list></back></article>
